EN 14110 Methanol content by HS
From LEAP
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|description = Determination of Methanol content by Headspace | |description = Determination of Methanol content by Headspace | ||
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=== Overview === | === Overview === | ||
EN14110 describes the required method for methanol determination in biodiesel. | EN14110 describes the required method for methanol determination in biodiesel. | ||
| + | A high methanol content can raise vapor pressure and increase flammability in biodiesel. | ||
=== Significant Markets === | === Significant Markets === | ||
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'''EN Method 14110''' | '''EN Method 14110''' | ||
| - | + | EN 14110: Fat and oil derivatives – Fatty Acid Methyl Esters (FAME) - Determination of methanol content | |
| - | Biodiesel can consist of | + | Biodiesel can consist of different fatty acid methyl esters, depending on the oils used during production. For the determination of methanol in such a complex matrix, gas chromatography in combination with headspace injection is the recommended method. This enables separation of low-boiling methanol from the high-boiling fatty acid methyl esters already during the sample preparation step. |
The biodiesel samples are heated in a gas-tight 20 mL vial. Methanol is a low-boiling point compound and is enriched in the gas-phase while the high-boiling point compounds remain in the liquid phase. After a specific time, equilibrium is reached and a constant volume can be sampled from the gas-phase (headspace) of the vial and injected into the GC system. | The biodiesel samples are heated in a gas-tight 20 mL vial. Methanol is a low-boiling point compound and is enriched in the gas-phase while the high-boiling point compounds remain in the liquid phase. After a specific time, equilibrium is reached and a constant volume can be sampled from the gas-phase (headspace) of the vial and injected into the GC system. | ||
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| + | GC Run time is approximately 10 minutes | ||
=== Photos === | === Photos === | ||
| + | [[Image:HP6890.jpg|200px|thumb|left|Representative System shown with Agilent 7890 and Combi PAL]] <br><br><br><br><br><br><br> | ||
| - | [ | + | === Software Control === |
| + | Currently the [http://www.leapwiki.com/mediawiki/index.php?title=Category:Combi COMBI ] [http://leapwiki.com/mediawiki/index.php?title=Category:PAL PAL] and runs on via the hand held due to the desire for look ahead functionality. | ||
| - | + | The incubation time is 45 minutes and the GC runtime is approximately 10 minutes | |
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Can also be run under Cycle Composer or Agilent CTC control software without look ahead functionality. | Can also be run under Cycle Composer or Agilent CTC control software without look ahead functionality. | ||
| + | <br/> <br/> <br/> <br/> <br/> <br/> <br/><br/><br/> | ||
| - | + | === Screenshots === | |
| - | + | ||
| - | == Screenshots == | + | |
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<gallery> | <gallery> | ||
Image:hs1.png | Cycle Composer method parameters | Image:hs1.png | Cycle Composer method parameters | ||
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| - | == Useful links == | + | ===Useful links === |
| + | [[Image:Www icon.png|40px]] [http://www.4cleanfuels.com/biofuels/BioDQuality8-07/FQ_workshop-PiedmontBioFuels.pdf An overview of all tests that must be run by Piedmont Biofuels] | ||
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| + | [[Image:Www icon.png|40px]] [http://www.chem.agilent.com/cag/prod/GC/Biodiesel_QR.pdf A good general reference site by Agilent] | ||
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| + | [[Image:Www icon.png|40px]] [http://biodiesel.engr.uconn.edu/home/Stuart.pdf UCONN.com A good general reference site on Biodiesel ASTM Methods] | ||
| - | + | [[Image:Www icon.png|40px]] [http://www.biodiesel.orgwww.biodiesel.org A good general reference site on Biodiesel ] | |
| - | + | [[Image:Www icon.png|40px]] [http://www.biodieselmagazine.com/plant-list.jsp Biodiesel Plant Listing ] | |
| - | + | [[Image:Www icon.png|40px]] [http://www.biodieselconference.org/2009/default.asp Biodiesel Conference 2009 ] | |
| - | + | === Videos of PAL === | |
| + | <br> | ||
| + | [[Image:Movie Icon.png|40px]] | ||
| + | [http://www.youtube.com/user/LEAPTechnologies#g/u LEAP's PAL Application Videos on YouTube] | ||
| + | <br> | ||
| - | + | ---- | |
| - | + | {{logo}} | |
| - | + | LEAP provides automated workstation instrumentation solutions based on the LEAP CTC PAL X, Y, Z syringe only autosampler robot from LEAP Technologies. This extremely flexible, precise, and adaptable liquid handling robotic platform is available in a variety of lengths and options depending on the requirements of your sample preparation and injections for your UHPLC, LC or GC chromatography.LEAP offers full support and service for the PAL platform in addition to being able to write custom macros, cycles, and scheduling to your applications. Please contact LEAP Technologies on how we can help you get maximized throughput with flexible pipetting automation solutions. | |
| - | + | === Contact LEAP === | |
| + | {{contact|topic=LEAP and the PAL Platform}} | ||
| + | [[Category: Biofuel]] | ||
| + | [[Category:Application_Solutions]] | ||
| + | [[Category:Cycle Composer]] | ||
| + | [[Category:Gas Chromatography]] | ||
| + | [[Category:Chronos]] | ||
Current revision
| Biofuels |
| Application Type | |
| Sample Inject | |
| Application ID | |
| Biodiesel EN14110 | |
| Description | |
| Determination of Methanol content by Headspace |
Contents |
Overview
EN14110 describes the required method for methanol determination in biodiesel. A high methanol content can raise vapor pressure and increase flammability in biodiesel.
Significant Markets
- Biodiesel Manufactures
- Biodiesel Blenders
- Biodiesel Distributors
- Biofuels CROs
- Fleet Managers
EN Method 14110
EN 14110: Fat and oil derivatives – Fatty Acid Methyl Esters (FAME) - Determination of methanol content
Biodiesel can consist of different fatty acid methyl esters, depending on the oils used during production. For the determination of methanol in such a complex matrix, gas chromatography in combination with headspace injection is the recommended method. This enables separation of low-boiling methanol from the high-boiling fatty acid methyl esters already during the sample preparation step.
The biodiesel samples are heated in a gas-tight 20 mL vial. Methanol is a low-boiling point compound and is enriched in the gas-phase while the high-boiling point compounds remain in the liquid phase. After a specific time, equilibrium is reached and a constant volume can be sampled from the gas-phase (headspace) of the vial and injected into the GC system.
GC Run time is approximately 10 minutes
Photos
Software Control
Currently the COMBI PAL and runs on via the hand held due to the desire for look ahead functionality.
The incubation time is 45 minutes and the GC runtime is approximately 10 minutes
Can also be run under Cycle Composer or Agilent CTC control software without look ahead functionality.
Screenshots
 Cycle Composer method parameters |
Useful links
An overview of all tests that must be run by Piedmont Biofuels
A good general reference site by Agilent
UCONN.com A good general reference site on Biodiesel ASTM Methods
A good general reference site on Biodiesel
Videos of PAL
LEAP's PAL Application Videos on YouTube
LEAP provides automated workstation instrumentation solutions based on the LEAP CTC PAL X, Y, Z syringe only autosampler robot from LEAP Technologies. This extremely flexible, precise, and adaptable liquid handling robotic platform is available in a variety of lengths and options depending on the requirements of your sample preparation and injections for your UHPLC, LC or GC chromatography.LEAP offers full support and service for the PAL platform in addition to being able to write custom macros, cycles, and scheduling to your applications. Please contact LEAP Technologies on how we can help you get maximized throughput with flexible pipetting automation solutions.
Contact LEAP
 Contact LEAP
For additional information about LEAP and the PAL Platform, please contact LEAP Technologies. |
